nH2 = 2.24/22.4 = 0.1 (mol) 

Zn + 2HCl => ZnCl2 + H2 

ZnO + 2HCl => ZnCl2 + H2O 

nZn = nH2 = 0.1 (mol) 

=> mZn = 6.5 g

mZnO = 14.6 - 6.5 = 8.1 (g) 

nZnO = 0.1 (mol)  

%Zn = 6.5/14.6 * 100% = 44.52%

%ZnO = 55.48%

nHCl = 0.1*2 + 0.1*2= 0.4 (mol) 

Vdd HCl = 0.4 / 0.5 = 0.8 l 

nH2=0,1mol

Zn + 2HCl -----> ZnCl2 + H2

0,1 mol 0,1 mol

mZn=0,1.65=6,5g

mZnO=14,6-6,5=8,1g

%mZn=\(\frac{6,5}{14,6}\).100=44,5%

%mZnO=55,5%

PTHH: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)

            \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

a) Ta có: \(n_{SO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_{Fe}=\dfrac{1}{15}\left(mol\right)\)

\(\Rightarrow\%m_{Fe}=\dfrac{\dfrac{1}{15}\cdot56}{13,6}\cdot100\%\approx27,45\%\) \(\Rightarrow\%m_{CuO}=72,55\%\)

b) Ta có: \(m_{CuO}=13,6-\dfrac{1}{15}\cdot56\approx9,9\left(g\right)\) \(\Rightarrow n_{CuO}=n_{H_2SO_4}=\dfrac{9,9}{80}=0,12375\left(mol\right)\)

*Làm gì có H₂SO₄ loãng đâu nhỉ ??

Tiếp bài của creeper nhé:

c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)

Theo PT₍₂₎: \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)

=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)

=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)

=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)

Theo đề, ta có: 

\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)

=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)

a, \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

m_{hh Zn và Fe} = 21,6-3 = 18,6 (g)

PTHH: Zn + H₂SO₄ → ZnSO₄ + H₂

Mol:      x                                           x

PTHH: Fe + H₂SO₄ → FeSO₄ + H₂

Mol:      y                                           y 

Ta có: \(\left\{{}\begin{matrix}65x+56y=18,6\\x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\%m_{Zn}=\dfrac{0,2.65.100\%}{21,6}=60,19\%\)

\(\%m_{Fe}=\dfrac{0,1.56.100\%}{21,6}=25,93\%\)

\(\%m_{Cu}=100-60,19-25,93=13,88\%\)

b,

PTHH: Zn + H₂SO₄ → ZnSO₄ + H₂

Mol:     0,2     0,2                            0,2

PTHH: Fe + H₂SO₄ → FeSO₄ + H₂

Mol:     0,1      0,1                            0,1 

\(m_{H_2SO_4}=\left(0,1+0,2\right).98=29,4\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{29,4.100\%}{25\%}=117,6\left(g\right)\)

c,m_{dd sau pư} = 21,6+117,6- (0,1+0,2).2 = 138,6 (g)

\(C\%_{ddZnSO_4}=\dfrac{0,2.161.100\%}{138,6}=23,23\%\)

\(C\%_{ddFeSO_4}=\dfrac{0,1.152.100\%}{138,6}=10,97\%\)

pthh: Zn+H2SO4→ZnSO4+H₂ (1)

         ZnO+H2SO4→ZnSO4+H₂O (2)

n H₂=0,2 (mol)

theo pt1 ta có nZn=nH₂=0,2 (mol)

⇒ mZn=0,2 .65=13 (g)→mZnO=21,1-13=8,1 (g) →nZnO=0,1 (mol)

Theo pt 1 nH2SO4=nZn=0,2(mol) (3)

Theo pt2 nH2SO4=nZnO=0,2 (mol) (4)

Từ 3,4 ⇒nHCl=0,4 (mol)

V H2SO4=0,4\1=0,4l =400ml

a, Ta có : \(n_{CO2}=\dfrac{V}{22,4}=0,1\left(mol\right)\)

\(BTNT\left(C\right):n_{MgCO3}=n_{CO2}=0,1\left(mol\right)\)

\(\Rightarrow m_{MgCO3}=n.M=8,4\left(g\right)\)

\(\Rightarrow m_{MgO}=8\left(g\right)\)

b, Thấy sau khi phản ứng xảy ra thu được dung dịch A gồm \(MgSO_4\) và có thể còn \(H_2SO_4\) dư .

\(BTNT\left(Mg\right):n_{MgSO_4}=n_{MgCO3}+n_{MgO}=0,3\left(mol\right)\)

\(PTHH:MgSO_4+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2\downarrow+BaSO_4\downarrow\)

.................0,3............0,3..................0,3..................0,3.............

\(\Rightarrow m_{\downarrow}=m_{Mg\left(OH\right)2}+m_{BaSO4}=87,3\left(g\right)\)

Mà \(\left\{{}\begin{matrix}m\downarrow=110,6\left(g\right)>87,3g\\n_{Ba\left(OH\right)2}=C_M.V=0,45>n_{Ba\left(OH\right)2pu}\left(0,3mol\right)\end{matrix}\right.\)

=> Dung dịch A vẫn còn H2SO4 dư và mol BaSO4 được tạo ra tiếp là :

\(n_{BaSO4}=\dfrac{110,6-87,3}{M}=0,1\left(mol\right)\)

\(PTHH:H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)

..................0,1............0,1...............0,1........................

Lại có : \(n_{Ba\left(OH\right)2}=0,45\left(mol\right)\)

=> Trong dung dịch B còn có Ba(OH)2 dư ( dư 0,45 - 0,3 - 0,1 = 0,05mol)

\(\Rightarrow C_{MBa\left(OH\right)2}=\dfrac{n}{V}=\dfrac{0,05}{0,5}=0,1\left(M\right)\)

Vậy ...

a.\(n_{H_2}=\dfrac{7,28}{22,4}=0,325mol\)

Gọi \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Zn}=y\end{matrix}\right.\) \(\left(mol\right)\)  \(\rightarrow27x+65y=10,55\left(g\right)\) (1)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

 x                                 1/2 x          3/2 x       ( mol )

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

 y                            y               y     ( mol )

\(\rightarrow\dfrac{3}{2}x+y=0,325\left(mol\right)\) (2)

\(\left(1\right);\left(2\right)\rightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,15.27}{10,55}.100\%=38,38\%\\\%m_{Zn}=100\%-38,38\%=61,62\%\end{matrix}\right.\)

b.\(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,15=0,075\\n_{ZnSO_4}=0,1\end{matrix}\right.\) ( mol )

\(\left\{{}\begin{matrix}C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,075}{0,8}=0,09M\\C_{M_{ZnSO_4}}=\dfrac{0,1}{0,8}=0,125M\end{matrix}\right.\)